Catalytic C-H activation by RhCI(CO)( PMe&-hv system
نویسندگان
چکیده
RhC1(CO)(PMe3)2 under irradiation is a powerful catalyst which can functionalize hydrocarbons including alkanes under mild conditions. The reaction with carbon monoxide leads to the formation of the corresponding aldehyde. Alkanes react regioselectively at the terminal methyl group. The reaction of alkanes under inert atmosphere results in the formation of alkenes with a concomitant evolution of dihydrogen. Terminal alkene is obtained from n-alkane in the presence of excess amount of PMe3 ligand. The irradiation is essential to cause the catalytic C-H activation.
منابع مشابه
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